It's the wrong isotope - bombs use Pu-239, while RTGs use Pu-238.
There, fixed that for you. Reactors will readily burn Pu-239. They will also burn Pu-240, and Pul-238 and whatever other isotope. To fetch "usable" Pu from a reactor requires lots of effort, but to use it, not so much. You can just mix it with initial fuel and be done with it.
Only bombs use Pu-239 only. And it takes nasty, expensive processing (and lots of it) to fetch Pu-239 and avoiding Pu-240. It is one of the reasons for those leaks at Hanford. Pu-240 contamination makes Pu nukes go "fuzz fuzz", like No
Source: http://rss.slashdot.org/~r/Slashdot/slashdotScience/~3/7VlGFWoRxS8/story01.htm
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